1.27 How many isomeric esters, including structural isomers and stereoisomers, can be made with the molecular formula C5H10O2, if methanoic acid is one of the two reactants used?

1.10 The equation for the reaction between carbon monoxide and hydrogen is shown. CO(g) + 3H2(g) CH4(g) + H2O(g) What are the units of Kp for this reaction?     Right-click on the button to open the data booklet in a new tab.     

1.14 The solids sodium chloride and sodium iodide both react with concentrated sulfuric acid at room temperature.   With NaCl, the products are NaHSO4 and HCl. With NaI, the products are NaHSO4, HI, I2, SO2, H2O, S and H2S.   What is the best explanation for this difference in products?

QUESTION 4 Using the given skeletal formula, answer the questions.   Right-click on the button to open the data booklet in a new tab.      4.1 Give the skeletal formula of a structural isomer. 4.2 Give the skeletal formula of a functional isomer   From the following structures:   Right-click on the button to open the data booklet in a new tab.   Right-click on the button to open the data booklet in a new tab.        4.3 Identify the type of isomer.    

1.5 Carbon and silicon have the same outer electronic structure. Why is a Si–Si bond weaker than a C–C bond?

QUESTION 5   Compounds containing different halogen atoms covalently bonded together are called interhalogen compounds.   5.1 One interhalogen compound can be prepared by the reaction between iodine and fluorine. This compound has Mr = 222 and the percentage composition by mass is: F, 42.8; I, 57.2. Calculate the molecular formula of this interhalogen compound. 5.2 Another interhalogen compound has the formula ICl. Draw a ‘dot-and-cross’ diagram of a molecule of this compound, showing outer shell electrons only. Explain whether or not you would expect this molecule to be polar.      

1.20 Which stage in the free radical substitution of ethane by chlorine has the lowest activation energy?     Right-click on the button to open the data booklet in a new tab.    

1.22 Chlorofluorocarbons damage the ozone layer by undergoing reactions with a free radical mechanism. The first stage of this is initiation. Which equation is most likely to be the initiation stage when chlorofluoromethane is involved in such a reaction?     Right-click on the button to open the data booklet in a new tab.     

QUESTION 6   When 2.00 mol of PCl5(g) are decomposed at 450 K and 1.00 × 105 Pa the resulting equilibrium mixture contains 0.800 mol of Cl2 (g).   PCl5 (g) < == > PCl3 (g) + Cl2 (g)   6.1 Calculate the partial pressure of phosphorus (V) chloride, pPCl5, in this equilibrium mixture. 6.2 Write the expression for the equilibrium constant, Kp, for the decomposition of PCl5(g).    

1.24 Which organic compound would not give either a yellow precipitate when treated with alkaline aqueous iodine or an orange precipitate when treated with 2,4-dinitrophenylhydrazine reagent?